Expressions are derived which estimate the systematic error involved in the determination of the activation energy by the initial rise method. It has been shown that the general belief that the initial rise method does not depend on the order of kinetics is rather a misconception if one takes the value of E thus determined in a quantitative sense. The applicability of these expressions has not only been discussed but also tested for some experimental peaks.
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Singh et al. (1988) studied this question.
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