An all-solid-state switchable mirror with thin film was prepared for basic research on a new type of smart window. The device has a multilayer of /indium tin oxide/glass and can switch reversibly from a reflective state to a transparent one. The durability of the device was investigated by a cyclic switching test. Though a transmittance change was slightly decreased, the device showed high durability up to 2000 switching cycles. We found that the degradation was related with the damaged surface of thin film and the diffusion of Ni and Pd atoms into thin film during a cyclic switching test.
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Tajima et al. (2007) studied this question.
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