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unit exerts greater stress on the Hofmann layer, leading to the antiferro-elastic interactions. Additionally, the asymmetric host-guest interactions contribute to the stepwise SCO properties. Thus, the incorporation of asymmetric bisubstituted ligands into 2D Hofmann-type systems represents a viable and cost-effective strategy for the development of multi-step SCO materials.
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Wu et al. (2025) studied this question.
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