Nature of cyanoargentate bridges defining spin crossover in new 2D Hofmann clathrate analogues

This is the authors' abstract. We don't add key points for this paper.

, which induce the creation of supramolecular 3D frameworks. The synergy between metallophilic interactions and the spin transition is also confirmed by the variation of Ag⋯Ag distances during spin crossover. The characterization of such analogues allowed us to analyze in detail the effect of the cyanometallic bridge on the structure of new frameworks and on the bistability in Hofmann-like complexes.