A new spectral resonance of metallic nanorods

The extinction, integrated scattering, and absorption spectra of gold and silver nanorods with random and regular orientation are studied. The calculations are performed for spheroids, circular cylinders, circular cylinders with hemispherical ends ( T -matrix method), and rectangular prisms (discrete dipole approximation). A new quadrupole resonance is discovered that arises between the usual plasmon dipole resonances excited by a field longitudinal or transverse with respect to the symmetry axis. The new resonance can be excited only by a TM incident wave and is the greatest for orientation of the symmetry axis of the particle at an angle of 54° with respect to the light beam.