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Nonoxidative methane conversion into aromatic hydrocarbons over ZSM-5-type high-silica zeolites modified with nanosized powders of molybdenum (4.0 wt %) and silver (0.1–0.5 wt %) is reported. The acidic properties of the catalysts have been investigated by temperature-programmed ammonia desorption. The microstructure and composition of the Ag-Mo/ZSM-5 catalytic systems have been studied by high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy. The doping of the Mocontaining zeolite with silver enhances its activity and stability in nonoxidative methane conversion into aromatic hydrocarbons.
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Восмериков et al. (2011) studied this question.
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