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We investigate the impact of phonon grain boundary scattering in our thermal conduction measurements carried out on polycrystalline niobium samples in the superconducting state and of two different sizes. A simple model is developed which takes into account the average grain size d , the Kapitza resistance R K at grain–grain boundaries and the number of grains n over which the measurements are performed. Our model predicts a strong spatial anisotropy in the thermal conductivity for which can account for the discrepancy in our experimental data. The analysis enables the determination of the Kapitza resistance R K at Nb grain–grain boundaries. We show that with increasing temperature the grain boundary resistance remains dominant relative to the bulk thermal resistance.
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Jay Amrit (2006) studied this question.
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