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By the use of a bromomethyl-cyclohexane derivative (7), which was synthesized from d-camphor (5), as the starting compound, two kinds of chiral segments, i.e. segment A-I (3) and segment A-II (4), were synthesized. These segments are potentially versatile building blocks for construction of the left half of taxane-type diterpenoids.
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Kitagawa et al. (1984) studied this question.
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