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All articles of this category Stannyl radicals Bu 3 Sn???? are generated smoothly and selectively from the distannane Bu 3 Sn-SnBu 3 , when optimized triplet sensitizers and mild UV irradiation are used. This allows fine tuning of slow consecutive radical steps. For example, carbon-centred radicals produced by this way can favour slow intramolecular (cyclizations) or intermolecular additions to double bonds, or dimerization, when no or carefully adjusted H-donors are used. Typical examples are given.
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HARENDZA et al. (1993) studied this question.
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