Bioreduction of Precious Metals by Microorganism: Efficient Gold@N‐Doped Carbon Electrocatalysts for the Hydrogen Evolution Reaction

The uptake of precious metals from electronic waste is of environmental significance and potential commercial value. A facile bioreductive synthesis is described for Au nanoparticles (ca. 20 nm) supported on N‐doped carbon (Au@NC), which was derived from Au/Pycnoporus sanguineus cells. The interface and charge transport between Au and N‐doped carbon were confirmed by HRTEM and XPS. Au@NC was employed as an electrocatalyst for the hydrogen evolution reaction (HER), exhibiting a small onset potential of −54.1 mV (vs. RHE), a Tafel slope of 76.8 mV dec−1, as well as robust stability in acidic medium. Au@NC is a multifunctional electrocatalyst, which demonstrates high catalytic activity in the oxygen reduction reaction (ORR), as evidenced by an onset potential of +0.97 V, excellent tolerance toward methanol, and long‐term stability. This work exemplifies dual recovery of precious Au and fabrication of multifunctional electrocatalysts in an environmentally benign and application‐oriented manner.