Adsorption of micropollutants onto realistic microplastics: Role of microplastic nature, size, age, and NOM fouling

). The MP size also played a key role on its adsorption capacity, which was found to increase with decreasing the particle size (20-1000 μm). MPs aging (simulated by Fenton oxidation) led also to substantial changes on their sorption behavior. Oxidized MPs exhibited acidic surface properties which led to a strong decrease on the adsorption of the hydrophobic micropollutant (DCF) but to an increase with the hydrophilic one (MNZ). NOM fouling (WWTP effluent, river water, humic acid solution) led to a dramatic decrease on the MPs sorption capacity due to sorption sites blocking. Finally, the increase of pH or salinity of the aqueous medium increased the micropollutants desorption.