Metallkomplexe mit funktionalisierten Schwefelliganden, II . Ruthenium(II)-benzylthiosulfinato Komplexe. Kristallstrukturanalyse von Cp(Ph3P)2Ru[S—S(O)—CH2C6H5]/Metal Complexes of Functionalized Sulfur Containing Ligands, II. Synthesis of Ruthenium (II) B enzyl-thiosulphinato Complexes. X-Ray Structure Determination of Cp(Ph3P)2Ru[S—S(O)—CH2C6H5]

(2)) CpRu(PPh3)(L)(SH) (L = PPh3 (1), CO compounds react with N-(benzylsulphinyl) phthalim ides to give the chiral complexes CpRu(PPh3)(L)[S-S(O)-CH2-Ph] (4, 5). For 5, a diastereoselectivity of 10:3 is observed. The compounds 4, 5 have been characterized by their spectroscopic data. The X-ray structure d etermination of 4 shows sulphur-sulphur bond lengths of 204,4(4), 205,5(4) and 205,3(4) pm for three independent molecules.