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Building a three-dimensional magnet: The manganese(II)-mediated self-assembly of a ferromagnetically coupled dicobalt(II) metallacryptand provides the first example of an oxamato-bridged heterobimetallic ferrimagnet with a three-dimensional honeycomb open-framework structure hosting linear arrays of water-bridged lithium(I) guests (see picture; mpba=1,3-phenylenebis(oxamato)).
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Pardo et al. (2008) studied this question.
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