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Based on the rigid and V‐shaped structure of Tröger's base, several dissymmetrical bis(bipyridine) ligands with both rigid and flexible spacer units have been synthesized, and their self‐assembly to double‐ and triple‐stranded helicates upon coordination to late transition metal ions has been investigated by NMR spectroscopic and ESI mass spectrometricmeans.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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Kiehne et al. (2008) studied this question.
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