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Complete saturation of the complexation capacity of cyclodextrins (CDs) is not required for micellization to take place. Investigation of the competition between micellization and complexation of surfactant monomers with β-CD (shown schematically) shows the presence of a high concentration of uncomplexed β-CD in equilibrium with the micellar system. This concentration increases with the length of the hydrocarbon chain of the surfactant.
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Dorrego et al. (2000) studied this question.
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