The syntheses and crystal structures of the following paratungstates-Z with different alkaline cations are reported and discussed: Na10[H2W12O42] · 20H2O (I), Na10[H2W12O42] · 27H2O (II), Na10[H2W12O47] · 28H2O (III), K10[H2W12O42] · 10H2O (IV), K6Na4[H2W12O42] · 13H2O (V), Cs6Na4[H2W12O42] · 16H2O (VI), Cs8Na2[H2W12O42] · 10H2O (VII), Cs8Na2[H2W12O42] · 12H2O (VIII), K3Na7[H2W12O42] · 24H2O (IX) and K5Na2[H2W12O42] · 12H2O (X). Priority has been set on the description of the coordination of the cations with the oxygen ligands H2W12O42 10- and H2O.
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Chrissafidou et al. (1995) studied this question.
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