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Besides the well-known argyrodite (Ag8GeS6), the new compound Ag2GeS3 could be synthesized from Ag2S-GeS2 mixtures. Ag2GeS3 crystallizes in an orthorhombic variant of the Wurtzite structure. Treatment of Ag2GeS3 in a AgI/AgCl-eutectic yields the quaternary compound Ag7GeS5I. Crystal data for Ag7GeS5I and some analogous compounds are given.
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Nagel et al. (1978) studied this question.
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