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At last, terminal imido complexes of manganese(V), the postulated intermediates in aziridination and amination reactions, have been prepared. The structurally well-defined (imido)manganese(V) corroles, 2 and 3, are easily synthesized from manganese(III) corroles with organic azides under photolysis conditions and react with electron-rich nucleophiles such as organic phosphanes.
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Eikey et al. (2002) studied this question.
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