Paper reports the results of X-ray diraction, X-ray absorption spectroscopy and the Mössbauer spectroscopy of metalinsulator lms sintered in Ar+O atmosphere evidencing the dierence in oxidation of FeCoZr nanoparticles embedded into Al2O3 and Pb(ZrTi)O3 matrixes.It is proved that Al2O3 matrix with high resistance to oxidation favors the formation of nanoparticles with metal coreoxide shell structure, while fully oxidized nanoparticles are observed inside Pb(ZrTi)O3 matrix.
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Julia A. Fedotova (2014) studied this question.
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