Negative capacitance in (FeCoZr)–(PZT) nanocomposite films

In this work, attention was focused on the inductive contribution to the real part of admittance G ( T , f ) in (Fe 0.45 Co 0.45 Zr 0.10 ) x (PZT) (1− x ) nanocomposite films deposited in a mixed argon–oxygen atmosphere. The observed G ( x , f , T ) dependences for the films on the dielectric side of the insulator–metal transition demonstrated the negative capacitance (NC) effect that was maximal for the nanocomposites with 0.40 < x < 0.60, where the metallic FeCoZr nanoparticles were totally oxidized. The NC effect was explained by a specially developed model for the ac hopping conductance of the electrons between the fully oxidized nanoparticles embedded in the PZT matrix. In accordance with the model, under the determined conditions the observed structure of nanocomposites led to an increase in the hopping electron mean lifetime on nanoparticles and hence to the possibility of positive angles of the phase shifts θ and a proper NC (inductive-like contribution) effect.