Heavy metal triangles: A class of actinide metallomacrocycles has been prepared in which three (C5Me5)2An (An=Th, U) fragments are coordinated by three 5,6-dicyano-1-methyl-3-(N-methylamino)isoindolyl bridging ligands (N blue). The tetravalent actinide centers form a triangular array in the products obtained through an unprecedented actinide-mediated cyclization of 1,2,4,5-tetracyanobenzene and subsequent self-assembly.
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Kiplinger et al. (2006) studied this question.
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