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The first direct measurement of a high resolution infrared absorption spectrum of an ionic complex, Ar–HN2+, is presented. The complex is generated in a continuous supersonic slit jet expansion with electron impact ionization. There have been observed 28 rotationally resolved transitions of the ν1+νs combination band in the 2501–2510 cm−1 region using a tunable diode laser. The band origin is determined at ν0=2505.4998(4) cm−1.
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Speck et al. (1997) studied this question.
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