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(4,4‘-Bipyridine)(triphenylphosphine)copper(I) chloride crystallizes in the triclinic space group P1̄ with a = 9.080(2) Å, b = 9.295(2) Å, c = 13.086(2) Å, α = 105.64(1)°, β = 105.30(1)°, and γ = 94.91(2)°. The structure is build up by dimeric Cu2Cl2 units with bridging Cl anions, which are connected by a 4,4‘-bipyridine to form a chain structure. The triphenylphosphine ligand completes the coordination sphere around the copper atoms.
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Lü et al. (1997) studied this question.
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