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The reduction of carbon tetrachloride by hydrated electrons, H atoms and reducing radicals has been investigated by pulse radiolysis conductivity methods. It has been found that one Cl® ion is formed per reducing species. A chain reaction is observed in the γ-radiolysis of solutions of CCl4 and iso-propanol, diethylether, and tetrahydrofurane. Mechanisms and kinetic data are discussed.
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Koster et al. (1971) studied this question.
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