High-Permittivity Silicone Composites with Different Polarization Titanates for Electric Field Modification

Polymer-matrix composites with ceramic fillers have various applications, one of which is the modification of the electric field. For this purpose, in this work, high-permittivity silicone composites with different polarization titanates were produced by mechanical mixing. The ceramic fillers chosen were CaCu3Ti4O12, KxFeyTi8−yO16, and BaTiO3 powders with high permittivity values and uniformly distributed in the polymer volume. Ceramic powders were studied by X-ray phase analysis and scanning electron microscopy methods. The proportion of ceramic powder was 25 wt.%. In parallel, composites were prepared with the addition of 25 wt.% glycerin. The functional properties of silicone composites were studied using the following parameters: the electrical strength and permittivity. The addition of all types of ceramic fillers, both together and without glycerin, led to a decrease in electrical strength (below 15 kV·mm−1); the exception is the sample with the CCTO without glycerin (about 28 kV·mm−1). The permittivity and the dielectric loss tangent of the composites increased as a result of the addition of fillers, especially noticeable in combination with glycerol in the low-frequency region. The obtained results are in good agreement with the literature data and can be used in the field of insulation in a high-permittivity layer to equalize equipotential fields.