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Abstract 5‐Amino‐4‐(substituted)iminomethyl‐1‐phenyl‐1, 2, 3‐triazoles 5 rearrange thermally to 4‐amidino‐substituted triazoles 6 instead of undergoing the Dimroth rearrangement to 5‐anilinotriazoles 3.
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L'abbé et al. (1989) studied this question.
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