A direct Ag−Sn bond has been established for the first time by X-ray crystallography for the dimeric complex [MeSi{SiMe2N(p-Tol)}3SnAg]2 (4) [d(Ag−Sn) =2.6567(7) Å], which is the product of a phosphine ligand redistribution reaction of MeSi{SiMe2N(p-Tol)}3SnAg(PPh3) (2).
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Findeis et al. (1997) studied this question.
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