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October 15, 2003Angewandte Chemie

Amide from Dinitrogen by In Situ Cleavage and Partial Hydrogenation Promoted by a Transient Zero‐Valent Thorium Synthon

Ilia Korobkov Sandro Gambarotta Glenn P. A. Yap

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Abstract

Reduktion durch Spaltung: Bei der Reduktion von Thorium(IV)-Komplex 1 mit Kaliumnaphthalid beobachtet man Spaltung und partielle Hydrierung von Distickstoff – vermutlich wird ein Thorium(0)-Amid-Komplex 2 gebildet (siehe Schema).

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Korobkov et al. (2003) studied this question.

synapsesocial.com/papers/6ab641d18f558a45c01961ed https://doi.org/10.1002/ange.200352205

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