The core of the matter: Reactions of Ag(PhCO2) with (Me2N)C6H4(SSiMe3) and E(SiMe3)2 (E=S, Se) lead to three clusters with new silver chalcogenide cores. For example, the core of [Ag88Se12(SC6H4NMe2)63(PPh3)6] (see picture) consists of bent hexagonal layers of selenium and sulfur atoms (yellow), with interstitial silver atoms (blue). The inorganic cores of the clusters are surrounded by organic shells.
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Chitsaz et al. (2006) studied this question.
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