A series of compounds containing the −N U N− group has been prepared. Their physical and chemical properties are reported. They adopt a trans configuration, and are thermally robust. The chemistry of some recently-prepared O U N− compounds is also described. These are the first examples of stable analogs of the uranyl ion UO 2 2+ . The factors that determine their stability are discussed.
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Brown et al. (1996) studied this question.
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