The birefringence of zinc oxide (ZnO) in the terahertz (THz) frequency range is measured using a parallel-polarization configuration THz time-domain spectrometer and compared with the result of an ab initio calculation. The measured birefringence of 0.180 at 1 THz shows good agreement with the calculated value of 0.170 from full phonon consideration, both of which are about 20 times larger than the birefringence in the visible range. It is found that the difference of the transverse optical and longitudinal optical (TO–LO) phonon splitting between the optical phonon branches ( A 1 and E 1 ) predominantly contributes to the huge birefringence of ZnO in the THz frequency region.
No takes yet. Share an insight, caveat, or question.
Kim et al. (2011) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: