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In this account, the author describes the synthetic efforts of his group on the preparation and functionalization of corrole derivatives. The work started with beta-alkylcorroles and continued with the preparation of 5,10,15-triarylcorroles. The peripheral functionalization of both the beta-alkyl- and meso-triarylcorroles is described, together with several examples of the intriguing and unexpected reactivity of this deceptive macrocycle in these reactions.
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Roberto Paolesse (2008) studied this question.
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