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Rotational structure in the 0-0, 1-0 and 0-1 bands of the A-X system and in the 0-0 and 1-1 bands of the B-X and C-X systems of MgF has been analysed. A-type doubling is observed in the one component of the A 2 II-X 2 Σ + system to be analysed and the variation of this with J suggests that the 2 II state is inverted. State C 2 Σ + appears to be a Rydberg state... (σ4s) and the ionization potential is estimated to be 7 6 8 eV. The internuclear distance in the ground state r e " is 1.750 Å.
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Barrow et al. (1967) studied this question.
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