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The recombination process of electric charges induced by stress release has been measured for cement samples embedded within quartz crystals to investigate the behavior of piezo-compensating charges in quartz-bearing rocks. The stress with a release constant τ of σ (t) = Δσ e—t/τ led to a theoretical pulse charge density q(t) = α Δσ{ερ/(τ — ερ)} (e—t/τ — e—t/ερ), where α, ε and ρ are the piezoelectric coefficient, permittivity and resistivity, respectively. The induced charges appeared on a sample measured with non-contacting electrodes depending on the number and orientation of synthetic quartz crystals, and two decay time constants of 0.25 and 2.5 s were obtained. The apparent piezoelectric coefficient for a sample with one piece of quartz was 1.0 × 10—15 C/N. However, the coefficients for samples with two pieces of quartz, which were arranged in the same or alternate directions, were 4.1 × 10—15 and 1.7 × 10—15 C/N, respectively. The behavior of piezo-compensating charges around quartz crystals in conductive cement suggests ferroelectric charge migration through the measurements of depolarization current.
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Matsuda et al. (2001) studied this question.
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