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In these notes, conjectures about the exact semi-classical expansion of eigenvalues of hamiltonians corresponding to potentials with degenerate minima, are recalled. They were initially motivated by semi-classical calculations of quantum partition functions using a path integral representation and have later been proven to a large extent, using the theory of resurgent functions. They take the form of generalized Bohr--Sommerfeld quantization formulae. We explain here their relation with the corresponding WKB expansion of the Schrödinger equation. We show how these conjectures naturally emerge from an evaluation of multi-instanton contributions in the path integral formulation of quantum mechanics.
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Jean Zinn‐Justin (2003) studied this question.
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