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Breaking the coke habit: By coupling thermal decomposition with catalytic partial oxidation, an effective method has been developed to convert solid biomass such as cellulose into synthesis gas (see photo of a hot Rh catalyst surface). Not only is the process fast (<70 ms), it also avoids the formation of coke, which is known to deactivate catalyst surface sites and block surface reactions.
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Dauenhauer et al. (2007) studied this question.
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