All articles of this category Addition of alkyl radicals to the acyclic glyoxylate imine 1 proceeded with a 70 : 30 stereoinduction, even at -78 °C. Addition to the cyclic imine 4b resulted in complete stereocontrol at -40 °C. glyoxylate imines - stereoinduction - radical addition - α-aminoesters
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Bertrand et al. (1998) studied this question.