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Reaction of 2,5-diphenylphospholide anion with 2-chloromethylpyridine affords the 1-(2-methylpyridine)phosphole ligand. The corresponding cationic Ru(cymene)Cl chelate complex catalyzes the hydrogen transfer process of ketones with very high TON and TOF numbers.
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Thoumazet et al. (2003) studied this question.
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