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Oxidative addition reactions of Pd(PPh 3 ) 4 on the pyrimidine nucleosides 3‘,5‘-di- O -acetylthymidine and 3‘,5‘-di- O -acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 were isolated and characterized by spectroscopic techniques. Moreover, the crystal structure of the trans -[PdCl(1-methyl thymine)(PPh 3 ) 2 ]·H 2 O ( 4 ) is reported.
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Romanelli et al. (2005) studied this question.
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