The 3-trichloromethyloxaziridine 7 reacts smoothly with lithium alkoxides, derived from a representative range of alcohols, transferring an NHBoc function to the oxygen to provide good to excellent yields of N-Boc-O-alkylhydroxylamines 8–16 by this new O-amination protocol.
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Foot et al. (2000) studied this question.
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