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January 1, 1996Chemical Communications

Synthesis and characterization of [NBu 4 ][Pt 3 (µ-PPh 2 ) 2 (C 6 F 5 ) 5 ]: an anionic cluster containing an unusual µ 3 -PPh 2 bridging system

Ester Alonso J. Forniés Consuelo Fortuño Antonio Martı́n A.G. Orpen

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Abstract

[NBu4]2[Pt2(µ-PPh2)2(C6F5)4] reacts with cis-[Pt(C6F5)2(thf)2](1:2 molar ratio) yielding [NBu4][Pt3(µ-PPh2)2(C6F5)5] which contains unusual µ3-PPh(1,2-η2-Ph)-κ3P phosphido and semi-bridging C6F5 ligands and two Pt–Pt bonds of length 2.899(1) and 2.772(1)Å.

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Cite This Study

Alonso et al. (1996) studied this question.

synapsesocial.com/papers/6adb2ccd0c47a6bdf3c34e51 https://doi.org/10.1039/cc9960000231

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Synthesis and reaction chemistry of the coordinatively unsaturated heterobimetallic complexes (CO)3(PPh3)Fe(.mu.-PCy2)Rh(PPh3)(CO) and (CO)4Fe(.mu.-PCy2)Rh(1,5-COD). Crystal and molecular structure of (CO)3(PPh3)Fe(.mu.-PCy2)Rh(PPh3)(CO)Original Research · 1989 · 24 citations
2Heterobimetallic phosphido-bridged complexes containing coordinatively unsaturated rhodium(I) and iridium(I) centers. Structural characterization of FeIr(.mu.-PPh2)(CO)5(PPh3)2Original Research · 1983 · 38 citations
3Isolation and x-ray structure of bis[(tetrahydrofuran)(.mu.2-di-tert-butylphosphido)(.mu.3-di-tert-butylphosphido)dilithium] ([Li2(.mu.3-tert-Bu2P)(.mu.2-tert-Bu2P)(C4H8O)]2) containing a staggered, planar lithium (Li4) unit. The first structurally characterized alkali metal diorganophosphideOriginal Research · 1983 · 79 citations
4Synthesis, x-ray structure, and reactivity of (NBu4)2[Pt2(.mu.-C6F5)2(C6F5)4].cntdot.H2O and (NBu4)[Pt2Ag(.mu.-C6F5)2(C6F5)4O(C2H2)2]. The first complexes containing bridging pentafluorophenyl groupsOriginal Research · 1988 · 56 citations
5Coordinational behavior of solvent-free diorganylzinc compounds: the remarkable x-ray structure of dimeric diphenylzincOriginal Research · 1990 · 78 citations

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