Possible inhibitive transition of negative temperature coefficient of resistivity states in pressurised quasi-2D trilayer nickelate: Jahn-Teller activation

La4Ni3O8 (La-438) can be formed by reducing mixed-valence Ni2+/ Ni3+ oxides La4Ni3O10, the n=3 members of the Ruddlesden-Popper-type series Rn+1NinO3n+1 (R = La). Critical dynamical transitional phases of electronic liquid in pressurised La4Ni3O8 driven by an initial electric field at low temperature regime considering a microscopically confined environment could happen once we studied by adopting the verified theory of quantum chemistry. The critical transitional temperatures linked to the almost zero-resistance transport of many condensed electrons and related to the dynamical transition at low-temperature regime in La4Ni3O8 (after removing negative temperature coefficient of resistivity or possible strong Mott's localisation) can be found by using specific activation volumes (induced by microscopically Jahn-Teller geometric distortions) and activation energies. We also address the possible high-temperature transport issue.