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The Mn2Cl95- mode of red emissive (C4NOH10)5Mn2Cl9·C2H5OH under thermal treatment will be cleaved into MnCl42- in the green emissive (C4NOH10)2MnCl4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.
Sun et al. (Tue,) studied this question.