The aim is to improve CO2 photocatalytic reduction performance in MOF-545 by modifying linker structures.
Chlorination of porphyrin linkers in MOF-545
Assessment of photocatalytic CO2 conversion under visible light
Evaluation of changes in electronic structure and band gap
Increased photocatalytic conversion of CO2 to formate
Enhanced efficiency attributed to altered electronic structure
Optimized band gap for better light absorption
Abstract
Chlorinating porphyrin linkers in MOF-545 boosts photocatalytic CO 2 -to-formate conversion under visible light by tuning the electronic structure and the band gap.