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2-Nitropropane functions as an effective nitric oxide donor to enable the catalytic aerobic sulfonyloximation of alkenes, producing structurally diverse β-sulfonyl oximes under mild conditions. Novelty: ClaimNovelty.METHODOLOGICAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

What question did this study set out to answer?

The aim is to explore the catalytic aerobic sulfonyloximation of alkenes using 2-nitropropane as a nitric oxide donor.

June 1, 2026Organic Letters0 citations

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Catalytic Aerobic Sulfonyloximation of Alkenes Enabled by the Nitric Oxide-Donor Role of 2-Nitropropane

PTPradip Ramdas Thorve HJHyeonmin Jo HKHun Young Kim

Key Points

The aim is to explore the catalytic aerobic sulfonyloximation of alkenes using 2-nitropropane as a nitric oxide donor.
Utilized 2-nitropropane to donate nitric oxide during reactions.
Employed mild conditions for the synthesis process.
Generated a variety of structurally diverse β-sulfonyl oximes.
Achieved a broad substrate scope with successful formation of β-sulfonyl oximes.
Demonstrated potential for nitrous oxide incorporation in radical reactions.

Abstract

isomerization and NO fragmentation. Structurally diverse β-sulfonyl oximes with broad substrate scope are obtained under mild conditions, highlighting the potential of controlled NO incorporation in radical transformations.

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Catalytic Aerobic Sulfonyloximation of Alkenes Enabled by the Nitric Oxide-Donor Role of 2-Nitropropane

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