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乙酸或甲酸在DMF中对Pd0(PPh3)4的氧化加成生成阳离子型氢化钯(II) trans-HPd(PPh3)2(DMF)+,并以乙酸根或甲酸根作为抗衡阴离子。这两个反应是可逆的。已测定了氧化加成反应的平衡常数和动力学常数。
Amatore et al. (Tue,) 研究了这一问题。
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