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Synthesis reveals unique coordination geometry in copper complexes, suggesting implications for electrochemistry.
Copper(I) and copper(II) complexes of 6,6'-bis(2-pyridylsulfanyl)-2,2'-bipyridine were synthesized. The X-ray structures revealed that the coordination geometry of the copper center was intermediate between tetrahedral and square planar for either oxidation state.
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Nagata et al. (2025) studied this question.
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