Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles

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This is a In Vitro Study study.

Nicola Hensiek; Dario Duwe; Merle Arrowsmith; Maximilian Michel; Holger Braunschweig

doi:10.1039/d5cc03752b

January 1, 2025Chemical Communications

Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles

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Key Points

The synthesis of bn-heterocycles efficiently utilizes oligoboranes and isonitriles with varied outcomes.
Key findings demonstrate the formation of distinct cb2n heterocycles, highlighting their structural diversity.
This approach employs thermal rearrangements of simple boranes, enhancing our understanding of these chemical reactions.
Implications point towards the potential for new synthetic routes in borane chemistry, warranting further exploration.

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Implication

Observational analysis shows how isonitriles form BN-heterocycles from boranes, indicating new paths for chemical synthesis.

Abstract

O-xylyl isonitrile readily inserts into one of the B–B bonds of simple, unactivated linear peraminotri- and tetraboranes. Subsequent thermal rearrangements yield two different types of CB2N heterocycles, a 1-azonium-2,4-diboretane-3-ide and...

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Hensiek et al. (2025) studied this question.

synapsesocial.com/papers/68a36c360a429f7973330882 https://doi.org/10.1039/d5cc03752b

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Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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