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A cycloaddition process reveals new structural insights into 3-azaborole motifs, indicating potential applications in materials science.
TheBN bond undergoes a [2+1+1] cycloaddition with two equiv of isocyanide, followed by reductive insertion of a third isocyanide into the BN bond, affording a 3-azaborolediide with pronounced charge delocalization onto the o -carborane framework.
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Xiang et al. (2026) studied this question.
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