Conformation-tunable hydrogen-bonded calix[2]aramide macrocycles: bridging aggregation-induced emission and charge-transfer host-guest chemistry

Ziying Lu; X. Ai; Yingxiao Mu; Mingbing Lian; Yanping Huo; Zecong Ye

doi:10.1039/d5qo00987a

January 1, 2025Organic Chemistry Frontiers

Conformation-tunable hydrogen-bonded calix[2]aramide macrocycles: bridging aggregation-induced emission and charge-transfer host-guest chemistry

View Full Paper

Ask AI

Bookmark

Share

Key Points

Aggregation-induced emission significantly improves the luminescence efficiency of the calix[2]aramide macrocycles, highlighting their potential in photonic applications.
The novel macrocycles were synthesized by linking crescent aramide tri-mers through methylene bridges, creating a unique structural design.
This study employed host-guest chemistry principles to explore charge-transfer mechanisms enabled by these macrocycles, expanding their use in advanced materials research.
Potential applications in optoelectronic devices may arise from the enhanced solid-state luminescence exhibited by the hydrogen-bonded macrocycles.

Implication

Two new hydrogen-bonded macrocycles enhance emission properties in solid-state, suggesting novel applications in charge-transfer systems.

Abstract

Two novel hydrogen-bonded calix[2]aramide ( C[2]A ) macrocycles were successfully synthesized by linking crescent aramide tri-mers via methylene bridges. The macrocycles exhibited aggregation-induced emission and clusterization-triggered emission phe-nomenon, enhanced solid-state luminescence efficiency...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Lu et al. (2025) studied this question.

synapsesocial.com/papers/68af53ffad7bf08b1eadaa31 https://doi.org/10.1039/d5qo00987a

View Full Paper

Ask AI

Bookmark

Share

Conformation-tunable hydrogen-bonded calix[2]aramide macrocycles: bridging aggregation-induced emission and charge-transfer host-guest chemistry

Key Points

Implication

Abstract

Discussion

Cite This Study

Conformation-tunable hydrogen-bonded calix[2]aramide macrocycles: bridging aggregation-induced emission and charge-transfer host-guest chemistry

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading